Article

Acetoxytropyliumbromid: Synthese, Strukturbeweis, Verhalten in Lösung

Peter EngelAbteilung für Kristallographie und Strukturlehre des mineralogisch-petrographischen Instituts der Universität Bern, 3012 Bern, Sahlistrasse 6U. KellerInstitut für Organische Chemie der Universität Bern, 3012 Bern, Erlachstrasse 9aPeter BiglerInstitut für Organische Chemie der Universität Bern, 3012 Bern, Erlachstrasse 9aMarkus NeuenschwanderAnfragen sind zu richten an P. E. (Röntgenstrukturanalyse) und M. N. (chemischer Teil)

Helvetica Chimica Actajournal1976en

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Abstract

Acetoxytropyliumbromide: Synthesis, Structural Evidence, Behaviour in Solution. Acetoxytropyliumbromide ( 9 ) is formed from tropone and acetylbromide. In solution the tropylium salt equilibrates with the educts, 9 being favored at low temperature in polar aprotic solvents. The structure of the title compound has been proved by X‐ray analysis, as well as by investigation of the 1 H‐NMR. spectra of solutions of 9 .

Topics

Chemical Synthesis and Reactions Chemical Synthesis and Analysis

Identifiers

DOI: 10.1002/hlca.19760590707

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