Article

ESR spectrum of Co2+ in Na2ZnCl4 · 3H2O

С. Н. ЛукинPhysicotechnical Institute, Academy of Sciences of the Ukrainian SSR, DonetskG. Ya. SamsonovaPhysicotechnical Institute, Academy of Sciences of the Ukrainian SSR, DonetskO. P. TeslyaPhysicotechnical Institute, Academy of Sciences of the Ukrainian SSR, DonetskG. A. TsintsadzePhysicotechnical Institute, Academy of Sciences of the Ukrainian SSR, Donetsk

Soviet Journal of Low Temperature Physicsjournal1981en

ABI

Abstract

The ESR spectrum of Co2+ ions in a Na2ZnCl4 · 3H2O crystal with tetrahedral coordination of the bivalent impurity ion is studied with the help of a spectrometer in the 4 mm wavelength range. The spectrum obtained is described by an axial spin Hamiltonian for an ion with S = 3/2, I = 7/2 and with parameters D = + (7.13 ± 0.03) cm−1, g‖ = 2.26±0.01, g⊥ = 2.37±0.02, A = (11 ± 1) · 10−4 cm−1, and B = (22±1)·10−4 cm−1.

Topics

Solid-state spectroscopy and crystallography Crystal structures of chemical compounds Nonlinear Optical Materials Research

Identifiers

DOI: 10.1063/10.0030562

Citations and references

Cited by 03 references

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