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Phonon spectra in ferroelastic KSc(MoO4)2

N. M. NesterenkoLow Temperature Physicotechnical Institute, Academy of Sciences of the Ukrainian SSR, Khar’kovV. I. FominLow Temperature Physicotechnical Institute, Academy of Sciences of the Ukrainian SSR, Khar’kovV. I. Kut’koLow Temperature Physicotechnical Institute, Academy of Sciences of the Ukrainian SSR, Khar’kov
ABI

Abstract

We report Raman scattering and IR reflection spectra of KSc(MoO4)2 and other trigonal molybdates and tungstates over the temperature range 4–300 °K. The changes in the spectra in the asymmetric phases are analyzed. The mechanism for the phase transition to the monoclinic phase is discussed.

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