Article

Kinetics of Chemical Reactions of Stressed Polymers

А. А. Попов Institute of Chemical Physics, USSR Academy of SciencesГ. Е. Заиков Institute of Chemical Physics, USSR Academy of SciencesN. N. Semeriov Institute of Chemical Physics, USSR Academy of Sciences

International Journal of Polymeric Materialsjournal1992en

ABI

Abstract

Abstract The effect of stress on the rate of chemical reactions is reviewed. It is shown that the sensitivity of the reaction rate to stress depends primarily on two factors; 1) the degree of change in the reactive site geometry, and 2) the energy content of the structural fragment affected by the reaction. Key Words: Stressed polymersreaction ratesozonationpolyolefins

Topics

Polymer Science and Applications Material Properties and Failure Mechanisms Tribology and Wear Analysis

Identifiers

DOI: 10.1080/00914039208041109

Citations and references

Cited by 02 references

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