Article

Bis[ethyl 2-cyano-2-(oxidoimino)acetate]bis(ethylenediamine)nickel(II) hexahydrate

Mikhail P. AzarkhNational Taras Shevchenko University, Department of Chemistry, Volodymyrska Str. 64, 01033 Kiev, UkraineNikolay M. DudarenkoNational Taras Shevchenko University, Department of Chemistry, Volodymyrska Str. 64, 01033 Kiev, UkraineIgor O. FritskyNational Taras Shevchenko University, Department of Chemistry, Volodymyrska Str. 64, 01033 Kiev, UkraineTurganbay S. IskenderovKarakalpakian University, Department of Chemistry, Universitet Keshesi 1, 742012 Nukus, UzbekistanJ. Świątek-KozłowskaMedical University of Wrocław, Department of Basic Medical Sciences, J. Kochanowskiego Str. 14, 51-601 Wrocław, Poland

Acta Crystallographica Section E Structure Reports Onlinejournal2006en

ABI

Abstract

The centrosymmetric neutral mononuclear title complex, [Ni(C5H5N2O3)2(C2H8N2)2]·6H2O, has the Ni centre in a distorted octahedral environment, defined by six N atoms belonging to two chelating ethylenediamine molecules and two cyano N atoms derived from cyanoxime ligands. The O atom of the deprotonated oxime group forms hydrogen bonds with two solvent water molecules.

Topics

Crystal structures of chemical compounds Metal complexes synthesis and properties Magnetism in coordination complexes

Identifiers

DOI: 10.1107/s1600536806048331

Citations and references

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