Article

Bis(7-methoxy-1-methyl-4,9-dihydro-3<i>H</i>-β-carbolinium) tetrachloridozincate

Zukhra C. KadirovaTashkent Chemical-Technological Institute, Navoi St 32, Tashkent 100011, UzbekistanStanislav A. ChepulskyNational University of Uzbekistan, Tashkent 100123, UzbekistanN.A. ParpievNational University of Uzbekistan, Tashkent 100123, UzbekistanSamat A. TalipovKhasan T. SharipovTashkent Chemical-Technological Institute, Navoi St 32, Tashkent 100011, Uzbekistan

Acta Crystallographica Section E Structure Reports Onlinejournal2010en

ABI

Abstract

In the title compound, (C(13)H(15)N(2)O)(2)[ZnCl(4)], also known as di(harmalinium) tetra-chloridozincate, the Zn(II) atom is in a distorted tetrahedral coordination of the chlorido ligands. In the cation, the meth-oxy and methyl groups are both coplanar with with rings to which they are attached [maximum deviations of 0.232 (4) and 0.259 (4) Å, respectively]. In the crystal, the alkaloid cations and metal complex anions inter-act by way of N-H⋯Cl hydrogen bonds involving each Cl atom, resulting in a network structure.

Topics

Crystal structures of chemical compounds Synthesis and bioactivity of alkaloids Metal complexes synthesis and properties

Identifiers

DOI: 10.1107/s1600536810010822

Citations and references

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