Synthesis of fluorescent carboxylic acid ligands for construction of monolayers on nanostructures

Abstract

Abstract Two new long-chain carboxylic acids (1, 2) bearing strong fluorescent group pyrene as ligands for Self-Assembled Monolayers (SAMs) have been synthesized. The multistep targeted synthesis is accomplished by use of Pyren-1-yl methylamine hydrochloride and employing simplified synthetic protocols. Compound 2 contains a chiral center purposely introduced along the atom chain in order to make it suitable for chiro-optical studies of the resulting SAMs.

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Identifiers

DOI

10.2478/s11532-012-0078-2

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