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Hydrothermal synthesis of two supramolecular inorganic–organic hybrid phosphomolybdates based on Ni(<scp>ii</scp>) and Co(<scp>ii</scp>) ions: structural diversity and heterogeneous catalytic activities

Luna PaulDepartment of Chemistry Jadavpur UniversityMalay DolaiDepartment of Chemistry Jadavpur UniversityAnangamohan PanjaIndiaMahammad AliDepartment of Chemistry Jadavpur University
New Journal of Chemistryjournal2016en
ABI

Abstract

Two new compounds (NHEPH<sub>2</sub>)<sub>5</sub>[Ni<sup>II</sup>(P<sub>4</sub>Mo<sub>6</sub>O<sub>31</sub>)<sub>2</sub>]·6H<sub>2</sub>O (<bold>1</bold>) and {(NHEPH<sub>2</sub>)<sub>2</sub>[Co<sup>II</sup>(H<sub>2</sub>O)<sub>6</sub>]}[P<sub>2</sub>Mo<sub>5</sub>O<sub>23</sub>]·2H<sub>2</sub>O (<bold>2</bold>) exhibited heterogeneous styrene oxidation by H<sub>2</sub>O<sub>2</sub> under mild conditions.

Topics

Polyoxometalates: Synthesis and ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsMetalloenzymes and iron-sulfur proteins

Identifiers

DOI
10.1039/c6nj00440g

Citations and references

Cited by 032 references
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