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Kinetics of mechanochemical dissolution of chromium in iron

E. P. YelsukovPhysicotechnical Institute, Ural Branch, Russian Academy of Sciences, ul. Kirova, 132, Izhevsk, 426000, RussiaA. L. Ul’yanovPhysicotechnical Institute, Ural Branch, Russian Academy of Sciences, Izhevsk, RussiaД. А. КолодкинPhysicotechnical Institute, Ural Branch, Russian Academy of Sciences, ul. Kirova, 132, Izhevsk, 426000, RussiaВ. Е. ПорсевPhysicotechnical Institute, Ural Branch, Russian Academy of Sciences, ul. Kirova, 132, Izhevsk, 426000, Russia
Colloid Journaljournal2016en
ABI

Abstract

The kinetics of solid Fe–Cr solution formation has been studied during mechanical alloying of Fe and Cr powders taken in an atomic ratio of 80: 20. X-ray diffraction and Mössbauer spectroscopy data have been analyzed within the framework of the energetic approach. It has been established that, in this system, reaction product yield N is related to mechanical energy dose D and specific surface area S of Fe nanograin boundaries in an ideal manner: N ~ D 2 at S ~ D and N ~ D at S = const.

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