Article

Role of electronic effects in forming the structure of the nitrilotrismethylenephosphonic complexes of 3d elements (Cr–Zn)

Ф. Ф. ЧаусовInstitute of Mechanics, Ural Branch, Russian Academy of Sciences, Izhevsk, 426034, RussiaН. В. СомовLobachevsky National Research University, Nizhny Novgorod, 607220, RussiaЕ. А. НаймушинаIzhevsk State Technical University, Izhevsk, 426069, RussiaИ. Н. ШабановаPhysicotechnical Institute, Ural Branch, Russian Academy of Sciences, Izhevsk, 426001, Russia

Bulletin of the Russian Academy of Sciences Physicsjournal2017en

ABI

Abstract

Two series of nitrilotrismethylenephosphonic complexes of 3d elements, [MII(H2O)3{NH(CH2PO3H)3}]n (M = Cr–Zn) and Na8[MII{N(CH2PO3)3}]2 nH2O (M = Co–Zn), are studied. A comparative analysis of their structural features showed the influence the Jahn–Teller effect has on the formation of the crystal structures, reactive capacities, and anticorrosive activities of these compounds.

Topics

Chemical Synthesis and Characterization Inorganic Chemistry and Materials Organometallic Compounds Synthesis and Characterization

Identifiers

DOI: 10.3103/s1062873817030078

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