Article

Synthesis, crystal structure and Hirshfeld surface analysis of a propyl 4-{[1-(2-methyl-4-nitrophenyl)-1<i>H</i>-1,2,3-triazol-4-yl]methoxy}benzoate copper(II) chloride complex

Muminjon HakimovNamangan State University, Boburshoh str. 161, Namangan, 160107, UzbekistanIlkhomjon OrtikovTulkinjon SattarovNamangan State University, Boburshoh str. 161, Namangan, 160107, UzbekistanB. TashkhodjaevInstitute of the Chemistry of Plant Substances, Uzbekistan Academy of Sciences, Mirzo Ulugbek Str. 77, Tashkent 100170, UzbekistanAkmaljon Tojiboev

Acta Crystallographica Section E Crystallographic Communicationsjournal2025en

ABI

Abstract

The core of the title complex, dichloridobis(propyl 4-{[1-(2-methyl-4-nitrophenyl)-1 H -1,2,3-triazol-4-yl]methoxy}benzoate)copper(II), [CuCl 2 (C 20 H 20 N 4 O 5 ) 2 ], which belongs to the copper(II) complex family, consists of two C 20 H 20 N 4 O 5 ligands and two chloride ligands arranged around the metal, forming a trans -dichlorido square-planar complex. In the crystal, the molecules are linked by C—H...Cl and C—H...O hydrogen bonds as well as by aromatic π–π stacking interactions into a three-dimensional network. To further analyse the intermolecular interactions, a Hirshfeld surface analysis was performed.

Topics

Crystal structures of chemical compounds Metal complexes synthesis and properties Lanthanide and Transition Metal Complexes

Identifiers

DOI: 10.1107/s2056989025001732

Citations and references

Cited by 019 references

Metrics — AkademScholar · Coming soon