Synergistic chaotropic effect and defect engineering promoting ultrahigh ionic conductivity in MOFs
Dongbo LiuChina-Uzbekistan Joint Laboratory on Advanced Porous Materials, School of Materials Science and Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, P. R. ChinaXiaomin LiChina-Uzbekistan Joint Laboratory on Advanced Porous Materials, School of Materials Science and Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, P. R. ChinaJunchao JiaChina-Uzbekistan Joint Laboratory on Advanced Porous Materials, School of Materials Science and Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, P. R. ChinaXingyu LongChina-Uzbekistan Joint Laboratory on Advanced Porous Materials, School of Materials Science and Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, P. R. ChinaJunpeng YanChina-Uzbekistan Joint Laboratory on Advanced Porous Materials, School of Materials Science and Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, P. R. ChinaM. XiaoChina-Uzbekistan Joint Laboratory on Advanced Porous Materials, School of Materials Science and Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, P. R. ChinaAziz B. IbragimovInstitute of General and Inorganic Chemistry, Uzbekistan Academy of Sciences, Tashkent 100170, UzbekistanJunkuo GaoChina-Uzbekistan Joint Laboratory on Advanced Porous Materials, School of Materials Science and Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, P. R. China
ABI
Abstract
ions, not only increasing ion mobility but also maintaining the water networks through dynamic hydrogen bonding reconstruction. These coordinated effects enable D-UiO-66-LiI to achieve ultrahigh ionic conductivities across wide temperature and humidity ranges.
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