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Electrospun Multifunctional Fibrous Membranes With Temperature‐Controlled, Electromagnetic Shielding, and Waterproof Properties

Jia-Jun TangNational & Local Joint Engineering Research Center for Textile Fiber Materials and Processing Technology Zhejiang Sci‐Tech University Zhejiang ChinaHaoyue WangNational & Local Joint Engineering Research Center for Textile Fiber Materials and Processing Technology Zhejiang Sci‐Tech University Zhejiang ChinaYang YangNational & Local Joint Engineering Research Center for Textile Fiber Materials and Processing Technology Zhejiang Sci‐Tech University Zhejiang ChinaSong LiNational & Local Joint Engineering Research Center for Textile Fiber Materials and Processing Technology Zhejiang Sci‐Tech University Zhejiang ChinaShanshan LiNational & Local Joint Engineering Research Center for Textile Fiber Materials and Processing Technology Zhejiang Sci‐Tech University Zhejiang ChinaJuming YaoNational & Local Joint Engineering Research Center for Textile Fiber Materials and Processing Technology Zhejiang Sci‐Tech University Zhejiang ChinaGuocheng ZhuNational & Local Joint Engineering Research Center for Textile Fiber Materials and Processing Technology Zhejiang Sci‐Tech University Zhejiang ChinaBaochun GuoDepartment of Polymer Materials and Engineering South China University of Technology Guangzhou ChinaParpiev KhabibullaDepartment of Technology of Textile Industry Products Namangan Institute of Textile Industry Namangan UzbekistanMing ZhangNational & Local Joint Engineering Research Center for Textile Fiber Materials and Processing Technology Zhejiang Sci‐Tech University Zhejiang China
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Abstract

ABSTRACT This study developed multifunctional fibrous membranes for wearable textiles. Using coaxial electrospinning, octadecane (Oct) was encapsulated within polylactic acid (PLA) to form core‐shell PLA@Oct (P 1 ) fibers for thermal regulation. MXene was then sprayed onto P 1 to create a conductive layer (P 1 M) for electromagnetic interference (EMI) shielding. Finally, a waterproof layer of PLA/polyvinylidene fluoride (PVDF) blended with fluorinated SiO 2 was electrospun atop P 1 M, resulting in the multilayer membrane P 1 MP 2 . The optimized membrane demonstrated a high latent heat of 111.73 J/g, an effective EMI shielding effectiveness of 32.68 dB in the X‐band, and a hydrophobic contact angle of 136.91°. This integration of temperature management, EMI shielding, and waterproof showcases certain potential for advanced wearable applications.

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