Article

Functionalization-Induced Solubility Collapse and Kinetic Partitioning Govern CNT Core-Shell Inversion in UHMWPE Microspheres

Moulay Rachid BabaaArts et Metiers Campus of Rabat (EAMR), Parc Technopolis, 11100 Sala Al Jadida, Morocco

ChemRxivrepository2025

ABI

Abstract

Functionalization-induced solubility collapse produces MWNTs/UHMWPE microspheres with size-dependent architectures. A bifunctional linker and a coupling agent trigger rapid phase segregation and MWNTs interfacial migration, yielding CNT-rich droplets. Larger droplets develop CNT-enriched shells, while smaller ones retain CNTs in their cores. SEM, TEM, and XRD confirm unique core-shell-corona structures.

Topics

Block Copolymer Self-Assembly Pickering emulsions and particle stabilization Surface Modification and Superhydrophobicity

Identifiers

DOI: 10.26434/chemrxiv-2025-tsgml-v2

Citations and references

Cited by 00 references

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