Skip to main content
Article

Dibenzoxazepine Anodic Determination and Removal on CuS Nanoparticles: A Theoretical Insight

Volodymyr V. TkachUniversity of Trás-os-Montes and Alto Douro, 5000-020, Quinta de Prados, Folhadela, Vila Real, PortugalMarta V. KushnirChernivtsi National University, 58001, Kotsyubynsky Str. 2, Chernivtsi, UkraineSílvio C. de OliveiraInstitute of Chemistry. Federal University of Mato Grosso do Sul, 79074 – 460, Av. Sen. Felinto Müller, 1555, Vila Ipiranga, Campo Grande, MS, BrazilIgor G. BiryukBukovinian State Medical University, 58001, Teatralna Sq, 9, Chernivtsi, UkraineТetyana B. SykyrytskaBukovinian State Medical University, 58001, Teatralna Sq, 9, Chernivtsi, UkraineYana G. IvanushkoBukovinian State Medical University, 58001, Teatralna Sq, 9, Chernivtsi, UkrainePetro I. Yagodynets´Chernivtsi National University, 58001, Kotsyubynsky Str. 2, Chernivtsi, UkraineAdriano O. da SilvaFederal University of the West of Pará, Juruti Campus, 68170 – 000, Rua Veríssimo de Souza Andrade, s/n, Juruti, PA, BrazilNataliia P. DereviankoMykhailo P`. ZavhorodniiVira M. OdyntsovaZaporizhzhia State Medical University, 69600, Mayakovsky Ave. 24, Zaporizhzhia, UkraineMykola P. KraskoZaporizhzhia State Medical University, 69600, Mayakovsky Ave. 24, Zaporizhzhia, UkraineInna M. ShevchenkoZaporizhzhia State Medical University, 69600, Mayakovsky Ave. 24, Zaporizhzhia, UkraineViktoriia M. LavrinenkoNational Pedagogical University of Ukraine, 02000, Pyrohov Str.,9, Kyiv, UkraineOleksii T. YermakNational Pedagogical University of Ukraine, 02000, Pyrohov Str.,9, Kyiv, UkraineL. N. NiyazovAbu Ali Ibn Sino Bukhara State Medical Institute, 705018, Navoi Str., 1, Bukhara, UzbekistanDilfuza M. MusayevaAbu Ali Ibn Sino Bukhara State Medical Institute, 705018, Navoi Str., 1, Bukhara, UzbekistanXayriddin KosimovAbu Ali Ibn Sino Bukhara State Medical Institute, 705018, Navoi Str., 1, Bukhara, UzbekistanOysha JabborovaAbu Ali Ibn Sino Bukhara State Medical Institute, 705018, Navoi Str., 1, Bukhara, UzbekistanGulandom SagdullayevaAbu Ali Ibn Sino Bukhara State Medical Institute, 705018, Navoi Str., 1, Bukhara, UzbekistanElvina SharipovaAbu Ali Ibn Sino Bukhara State Medical Institute, 705018, Navoi Str., 1, Bukhara, UzbekistanTetiana V. MorozovaState Scientific Institution "Institute of Ecological Restoration and Development of Ukraine", Environment Remediation Section, Mytropolite Vasyl Lypkivsky Str. 35, 01001 Kyiv, UkraineOleksandr V. MudrakVinnytsya Regional Institute of Postgraduate Education, 21000, Hrushevskogo Str. 13, Vinnytsia, UkraineJarem R. GarciaState University of Ponta Grossa, Uvaranas Campus, Av. Gal. Carlos Cavalcanti, 4748, 84030-900, Ponta Grossa, PR, BrazilJosé Inácio Ferrão da Paiva MartinsEngineering Faculty of the University of Porto, 4200-465, Rua Dr. Roberto Frias, s/n, Porto, PortugalZholt O. KormoshVolyn National University, 43000, Voli Ave., 13, Lutsk, UkraineAlla V. GrekovaOdesa National Medical University, 65000, Valikhovsky Ln. 2, Odesa, UkraineYa. F. BurdinaOdesa National Medical University, 65000, Valikhovsky Ln. 2, Odesa, UkraineRuslan V. LavrikNational University of Life and Environmental Science of Ukraine, 03041, Heroiv Oborony Str, 15, Kyiv, Ukraine
ABI

Abstract

For the first time, the electroanalytical system for the electrochemical determination and removal of dibenzoxazepine chemical warfare agent on CuS-modified anode has been given. Two oxidation scenarios, including the electropolymerization and N-oxidation, are possible for dibenzoxazepine. Either way, both dibenzoxazepine and its N-oxide will be removed from the environment towards the polymer phase. The analysis of the electroanalytical process using linear stability theory and bifurcation analysis confirms that the steady-state stability allows us to use this process for both electroanalytical and electrocatalytic purposes.

Topics

Identifiers

Citations and references

Cited by 031 references