High H<sub>2</sub> and CH<sub>4</sub> Adsorption Capacity of a Highly Porous (2,3,4)-Connected Metal–Organic Framework
Zhiyong LuState Key
Laboratory of Coordination Chemistry, School
of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, ChinaLiting DuState Key
Laboratory of Coordination Chemistry, School
of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, ChinaKuanzhen TangState Key
Laboratory of Coordination Chemistry, School
of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, ChinaJunfeng BaiState Key
Laboratory of Coordination Chemistry, School
of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China
2013en
ABI
Abstract
A porous metal–organic framework [Cu6(BDPP)3(H2O)6] (BDPP = 3,5-bis(3,5-dicarboxylphenyl)-pyridine) (NJU-Bai10) was synthesized. NJU-Bai10 exhibits a high BET surface area of 2883 m2 g–1, the highest excess H2 volumetric adsorption of 48.0 g L–1 (60 bar, 77 K), and a high methane uptake of 198.6 cm3 cm–3 that surpasses the DOE target.
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