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Article

Metric geometry of equilibrium thermodynamics

Frank WeinholdDepartment of Chemistry, Stanford University, Stanford, California 94305
1975en
ABI

Abstract

It is shown that the principal empirical laws of equilibrium thermodynamics can be brought into correspondence with the mathematical axioms of an abstract metric space. This formal correspondence permits one to associate with the thermodynamic formalism a geometrical aspect, with intrinsic metric structure, which is distinct from that arising from graphical representations of equilibrium surfaces in phase space.

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Cited by 170 references