Strategies for Hydrogen Storage in Metal–Organic Frameworks
Jesse L. C. RowsellMaterials Design and Discovery Group, Department of Chemistry, Ann Arbor, MI 48109-1055, USAOmar M. YaghiMaterials Design and Discovery Group, Department of Chemistry, Ann Arbor, MI 48109‐1055, USA, Fax: (+1) 734‐615‐9751
2005en
ABI
Abstract
Increased attention is being focused on metal-organic frameworks as candidates for hydrogen storage materials. This is a result of their many favorable attributes, such as high porosity, reproducible and facile syntheses, amenability to scale-up, and chemical modification for targeting desired properties. A discussion of several strategies aimed at improving hydrogen uptake in these materials is presented. These strategies include the optimization of pore size and adsorption energy by linker modification, impregnation, catenation, and the inclusion of open metal sites and lighter metals.
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