Centrifugal barrier perturbation of the <i>n</i> f2F series in Ba II
Jean Patrick ConneradePhysics Department, Imperial College, London, S. W. 7M. W. D. MansfieldPhysikalisches Institut, Universität Bonn, Bonn, Germany
1975en
ABI
Abstract
Abstract Hartree-Fock calculations for the nf 2F0 series of Ba II are reported. Several of the nf wavefunctions are found to be shared between the inner and the outer wells of the double valley potential. The resulting anomalies in intensity, spin-orbit splitting and quantum defect provide a qualitative explanation for some recent observations.
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