Adiabatic Population Transfer with Control Fields
Mustafa DemirplakDepartment of Chemistry and the James Franck Institute, The University of Chicago, Chicago, Illinois 60637Stuart A. RiceDepartment of Chemistry and the James Franck Institute, The University of Chicago, Chicago, Illinois 60637
2003en
ABI
Abstract
This paper explores the benefit of using time dependent basis sets in the description of adiabatic population transfer between molecular states. Using a time dependent basis set formalism, we develop a counter-diabatic field paradigm that generates adiabatic population transfer for apparently unfavorable conditions. We also describe a time dependent perturbation approach to account for the effect of stochastic dephasing on adiabatic population transfer.
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Cited by 150 references