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Synthesis and electrochemical performance of hierarchically porous N-doped TiO2 for Li-ion batteries

George HasegawaDepartment of Energy & Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, JapanTatsuya SatoDepartment of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa, Sakyo-ku, Kyoto 606-8502, JapanKazuyoshi KanamoriDepartment of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa, Sakyo-ku, Kyoto 606-8502, JapanKazuki NakanishiDepartment of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa, Sakyo-ku, Kyoto 606-8502, JapanTakeshi AbeDepartment of Energy & Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan
2014en
ABI

Abstract

Hierarchically porous N-doped TiO2 materials have been synthesized from macroporous inorganic–organic hybrid gels composed of titanium bridged with ethylenediamine. Homogeneously dispersed nitrogen in the precursor gel networks leads to TiO2 doped with a large amount of nitrogen, which delivers high discharge capacity and good cycle performance as a negative electrode for Li-ion batteries.

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Cited by 30 references