Bis(acetylacetonato-κ<sup>2</sup><i>O</i>,<i>O</i>′)(2-amino-1-methyl-1<i>H</i>-benzimidazole-κ<i>N</i><sup>3</sup>)oxidovanadium(IV)
Zukhra C. KadirovaNational University of Uzbekistan, Tashkent 100123, UzbekistanDilnoza S. RahmonovaNational University of Uzbekistan, Tashkent 100123, UzbekistanSamat A. TalipovJamshid AshurovN.A. ParpievNational University of Uzbekistan, Tashkent 100123, Uzbekistan
ABI
Abstract
The title mixed-ligand oxidovanadium(IV) compound, [VO(C(5)H(7)O(2))(2)(C(8)H(9)N(3))], contains a V(IV) atom in a distorted octahedral coordination, which is typical for such complexes. The vanadyl group and the N-heterocyclic ligand are cis to each other. The coordination bond is located at the endocyclic N atom of the benzimidazole ligand. Intra-molecular hydrogen bonds between the exo-NH(2) group H atoms and acetyl-acetonate O atoms stabilize the crystal structure.