Site-Selective Catalytic Carboxylation of Unsaturated Hydrocarbons with CO<sub>2</sub> and Water
Morgane GaydouInstitute
of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology, Av. Països Catalans 16, 43007 Tarragona, SpainToni MoragasInstitute
of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology, Av. Països Catalans 16, 43007 Tarragona, SpainFrancisco Juliá‐HernándezInstitute
of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology, Av. Països Catalans 16, 43007 Tarragona, SpainRubén Martı́nICREA, Passeig Lluïs
Companys, 23, 08010 Barcelona, Spain
2017en
ABI
Abstract
A catalytic protocol that reliably predicts and controls the site-selective incorporation of CO2 to a wide range of unsaturated hydrocarbons utilizing water as formal hydride source is described. This platform unlocks an opportunity to catalytically repurpose three abundant, orthogonal feedstocks under mild conditions.
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