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Iron Salts in the Catalyzed Synthesis of 5‐Substituted 1<i>H</i>‐Tetrazoles

Julien BonnamourInstitute for Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52056 Aachen, GermanyCarsten BolmInstitute for Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52056 Aachen (Germany), Fax: (+49) 241-8092-391
2009en
ABI

Abstract

Clicking iron: Cheap and environmentally friendly [Fe(OAc)(2)] is used for the catalysis of cycloadditions between aryl nitriles and trimethylsilyl azide to prepare substituted 1H-tetrazoles in good yield (see scheme).

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