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Experimental review: chemical reduction of graphene oxide (GO) to reduced graphene oxide (rGO) by aqueous chemistry

Léonard GuexDepartment of Fibre and Polymer TechnologyBenedetta Sacchi20133 MilanKevin PeuvotDepartment of Fibre and Polymer TechnologyRichard L. AnderssonDepartment of Fibre and Polymer TechnologyAmir Masoud PourrahimiDepartment of Fibre and Polymer TechnologyValter StrömKTH Royal Institute of TechnologyStefano Farris20133 MilanRichard T. OlssonDepartment of Fibre and Polymer Technology
2017en
ABI

Abstract

indicated that the reduction of epoxy or hydroxyl groups had a greater impact on the restoration of the conductive nature of the graphite structure in rGO. These findings were reflected in the dramatic change in the structural stability of the rGO nanofoams produced by freeze-drying. The reduction protocol in this study allowed to achieve the highest conductivity values reported so far for the aqueous reduction of graphene oxide mediated by sodium borohydride. The 4-probe sheet resistivity approach used to measure the electrical conductivity is also, for the first time, presented in detail for filtrate sheet assemblies' of stacked GO/rGO sheets.

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