Direct electrochemical defluorinative carboxylation of α-CF₃ alkenes with carbon dioxide

Abstract

-difluoroalkene moiety from a broad range of substrates. The synthetic utility is further demonstrated by gram-scale synthesis and elaboration to several value-added products. Cyclic voltammetry and density functional theory calculations were performed to provide mechanistic insights into the reaction.

Identifiers

DOI

10.1039/d0sc04091f

Citations and references