Activated persulfate and peroxymonosulfate based advanced oxidation processes (AOPs) for antibiotics degradation – A review
Zhila HonarmandradGdansk University of Technology, Faculty of Chemistry, Department of Process Engineering and Chemical Technology, 11/12 Narutowicza St., 80-233, Gdansk, PolandXun SunKey Laboratory of High Efficiency and Clean Mechanical Manufacture, Ministry of Education, School of Mechanical Engineering, Shandong University, Shandong, ChinaZhaohui WangShanghai Engineering Research Center of Biotransformation of Organic Solid Waste, Shanghai, 200241, ChinaMu. NaushadDepartment of Chemistry, College of Science, King Saud University, P.O. Box 2455, Riyadh, 11451, Saudi ArabiaGrzegorz BoczkajGdansk University of Technology, EcoTech Center, 11/12 Narutowicza St., 80-233, Gdansk, Poland
2022en
ABI
Abstract
Sulfate radical AOPs (SR-AOP) were successfully utilized in degradation of antibiotics in water and wastewater treatment. The review discusses details on SR-AOPs mechanisms and applications for antibiotics degradation. The progress in this field was discussed, highlighting the most promising developments and remaining challenges. The applicability of SR-AOPs was summarized revealing the most susceptible and persistent to oxidation groups of pharmaceuticals. Highest effectiveness was reported for degradation of pharmaceuticals on ppb level. Systems revealed a scavenging effect in case of oxidant dose 0.7mM of the PS and 2mM of PMS. Future development demands simple persulfates activation systems for real matrix treatment.
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