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Sound Attenuation and Dispersion near the Liquid-Gas Critical Point

Kyozi KawasakiDepartment of Physics and Department of Chemistry and Chemical Engineering, University of Illinois, Urbana, Illinois 61801
1970en
ABI

Abstract

The attenuation and dispersion of sound near the gas-liquid critical point are studied theoretically using the author's extended mode-mode coupling theory. The results differ in the different regions of the sound-wave frequency $f$ expressed in a dimensionless unit and of $\ensuremath{\epsilon}$, the dimensionless temperature distance from the critical point. The attenuation behaves as ${f}^{2}{\ensuremath{\epsilon}}^{\ensuremath{-}3\ensuremath{\nu}\ensuremath{-}\frac{\ensuremath{\alpha}}{2}}$ for $0\ensuremath{\le}f\ensuremath{\ll}{\ensuremath{\epsilon}}^{3\ensuremath{\nu}}$, and as ${f}^{2\ensuremath{-}\frac{2p}{3}}{\ensuremath{\epsilon}}^{\ensuremath{-}\frac{3\ensuremath{\alpha}}{2}}$ for ${\ensuremath{\epsilon}}^{3\ensuremath{\nu}}\ensuremath{\ll}f\ensuremath{\ll}{\ensuremath{\epsilon}}^{\ensuremath{\nu}}$, where $p$ is the exponent which appears in the wave-number ($\stackrel{\ensuremath{\rightarrow}}{\mathrm{k}}$)-dependent correlation of the order parameter expressed as ${A}_{1}{k}^{\ensuremath{-}2+\ensuremath{\eta}}+{A}_{2}{\ensuremath{\epsilon}}^{1\ensuremath{-}\ensuremath{\alpha}}{k}^{\ensuremath{-}2+\ensuremath{\eta}\ensuremath{-}\ensuremath{\rho}}$, when $k$ is much greater than the inverse correlation range of critical fluctuations. The relative sound-velocity change with $f$ behaves as ${f}^{\frac{3}{2}}{\ensuremath{\epsilon}}^{\ensuremath{-}\frac{9\ensuremath{\nu}}{2}}$ for $0\ensuremath{\le}f\ensuremath{\ll}{\ensuremath{\epsilon}}^{3\ensuremath{\nu}}$, as ${f}^{1\ensuremath{-}\frac{2p}{3}}{\ensuremath{\epsilon}}^{\ensuremath{-}\ensuremath{\alpha}}$ if $p\ensuremath{\le}\frac{3}{2}$, and as ${f}^{0}{\ensuremath{\epsilon}}^{0}$ if $p>\frac{3}{2}$ for ${\ensuremath{\epsilon}}^{3\ensuremath{\nu}}\ensuremath{\ll}f\ensuremath{\ll}{\ensuremath{\epsilon}}^{\ensuremath{\nu}+\frac{\ensuremath{\alpha}}{2}}$. The explicit expressions for the attenuation and dispersion are given for $f\ensuremath{\sim}{\ensuremath{\epsilon}}^{3\ensuremath{\nu}}$.

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