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Ultrasonic study of critical behavior in the binary liquid 3-methylpentane + nitroethane

C. W. GarlandDepartment of Chemistry and Center for Material Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139G. SanchezDepartment of Chemistry and Center for Material Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139
1983en
ABI

Abstract

The acoustic velocity and attenuation have been measured in a critical mixture of 3-methylpentane + nitroethane over the frequency range 1–17 MHz and the temperature range 0.004≤T−Tc≤13.5 K. No critical dispersion was observed in the velocity, which varied linearly with T. A substantial critical attenuation was well characterized as a function of the reduced frequency ω*≡ω/ωD over the range 10−1≤ω*≤106. The experimental data in this system are extensive enough to permit quantitative tests of the predictions of dynamic scaling theory, dynamic renormalization-group theory, and several versions of mode-coupling theory. Universality in the scaling function for the critical attenuation is demonstrated by comparison with comparable experimental results in two pure fluids.

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