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Ion-Exchange Sorption of Palladium(II) from Hydrochloric Acid Solutions in the Presence of Silver(I)

О. Н. КононоваInstitute of Nonferrous Metals and Materials Science, Siberian Federal University, 660025, Krasnoyarsk, RussiaE. V. DubaInstitute of Nonferrous Metals and Materials Science, Siberian Federal University, 660025, Krasnoyarsk, RussiaD. V. MedovikovInstitute of Nonferrous Metals and Materials Science, Siberian Federal University, 660025, Krasnoyarsk, RussiaА. С. КрыловKirensky Institute of Physics, Russian Academy of Sciences, Siberian Branch, 660036, Krasnoyarsk, Russia
2018en
ABI

Abstract

The sorptive extraction of palladium(II) chloride complexes in the presence of silver(I) chloride complexes from 2 and 4 M aqueous solutions of HCl with a series of Purolite anionites with different functional groups is studied. An anion exchange mechanism of sorption is identified from Raman spectroscopy data. Kinetic properties that are inherent to the investigated ionites and allow the elution of palladium(II) and silver(I) after their extraction in a dynamic mode are revealed.

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