New oligogermane with a five coordinate germanium atom: the preparation of 1-germylgermatrane
Kirill V. ZaitsevDepartment of ChemistryAndrei V. ChurakovMoscow, RussiaО. Х. ПолещукNational Research Tomsk Polytechnic UniversityYuri F. OprunenkoDepartment of ChemistryGalina S. ZaitsevaDepartment of ChemistrySergey S. KarlovDepartment of Chemistry
2014en
ABI
Abstract
The first example of an oligogermane, N(CH2CH2O)3Ge-Ge(SiMe3)3 (1), containing a hypercoordinate germanium atom was prepared and characterized by various methods (NMR, UV/vis, and X-ray analysis). The electronic structure of compound 1 was investigated via DFT calculations.
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