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Work: NiFe<sub>2</sub>O<sub>4</sub>@SiO<sub>2</sub>@ZrO<sub>2</sub>/SO<sub>4</sub><sup>2−</sup>/Cu/Co nanoparticles: a novel, efficient, magnetically recyclable and bimetallic catalyst for Pd-free Suzuki, Heck and C–N cross-coupling reactions in aqueous media