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Effect of mesoscale phase contrast on fatigue-delaying behavior of self-healing hydrogels

Xueyu LiGlobal Station for Soft Matter, Global Institution for Collaborative Research and Education (GSS, GI-CoRE), Hokkaido University, Sapporo, JapanKunpeng CuiInstitute for Chemical Reaction Design and Discovery (WPI-ICReDD), Hokkaido University, Sapporo, JapanTakayuki KurokawaFaculty of Advanced Life Science, Hokkaido University, Sapporo, JapanYa Nan YeGlobal Station for Soft Matter, Global Institution for Collaborative Research and Education (GSS, GI-CoRE), Hokkaido University, Sapporo, JapanTao Lin SunFaculty of Advanced Life Science, Hokkaido University, Sapporo, JapanChengtao YuGraduate School of Life Science, Hokkaido University, Sapporo, JapanCostantino CretonSorbonne UniversitéJian Ping GongFaculty of Advanced Life Science, Hokkaido University, Sapporo, Japan
2021en
ABI

Abstract

, is identified, correlated to the onset of non-affine deformation of the mesophase structure in a hydrogel without crack, which governs the slow-to-fast transition in fatigue crack growth. The detailed role played by the mesoscale structure on fatigue resistance provides design principles for developing self-healing, tough, and fatigue-resistant soft materials.

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