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Photocatalytic Activity, Antibacterial Effect, and Photoinduced Hydrophilicity of TiO<sub>2</sub> Films Coated on a Stainless Steel Substrate

Jimmy C. YuDepartment of Chemistry and Department of Biology, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong, ChinaWingkei HoDepartment of Chemistry and Department of Biology, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong, ChinaJun LinDepartment of Chemistry and Department of Biology, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong, ChinaHo-Yin YipDepartment of Chemistry and Department of Biology, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong, ChinaPo Keung WongDepartment of Chemistry and Department of Biology, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong, China
2003en
ABI

Abstract

Transparent TiO2 films on stainless steel prepared by dip coating in a nonionic microemulsions solution have been shown to have much higher photocatalytic activity than those coatings on glass. Fe3+ and Fe2+ ions, diffusing from stainless steel substrate into TiO2 films during high-temperature calcination, behave as dopants to significantly affect the films' photocatalytic activity. An optimum calcination condition, under which the amount of diffused Fe3+ and the ratio of Fe3+ to Fe2+ ions favor the film's photocatalytic reaction, was obtained. In addition, this TiO2 films also exhibits excellent photoinduced hydrophilicity and antibacterial effect for the sterilization of Bacillus pumilus. As stainless steel is a very common material, practical systems for pollution treatment and disinfection may be designed based on this enhanced coating.

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