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Work: Mononuclear Ni(II) and dinuclear Cd(II) complexes of 4-phenyl-2H-1,2,4-triazole-3-thione and Mn(II) catalyzed disulphide bond formation in 3,3′-dithiobis (4-phenyl-1,2,4-triazole): Syntheses, structural characterization, thermal analysis and DFT calculation