Nickel(II) Complexes with Azaheterocyclic Ligands and 2-Hydroxy-closo-Decaborate Anion [2-B10H9OH]2–
E. Yu. MatveevKurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, RussiaI. V. NovikovMIREA Russian Technological University, Lomonosov Institute of Fine Chemical Technologies, 119571, Moscow, RussiaAlexey S. KubasovKurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, RussiaВ. М. РетивовKurchatov Institute, National Research Center, 107076, Moscow, RussiaК. Yu. ZhizhinKurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, RussiaNikolay T. KuznetsovKurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia
2021en
ABI
Abstract
The interaction of (Bu4N)2[2-B10H9OН] with nickel(II) chloride in the presence of nitrogen-containing ligands, in particular, 1,10-phenanthroline, 2,2'-bipyridylamine, 2,2'-bipyridyl, and 2,6-diaminopyridine, has been studied. It has been shown that nickel(II) complexes containing the [2-B10H9OH]2– anion as a counterion are formed in the course of the reactions. The synthesized compounds have been investigated by elemental analysis, IR spectroscopy and X-ray diffraction.
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