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Work: Synthesis, structure and computational study of 5-[(prop-2-en-1-yl)sulfanyl]-1,3,4-thiadiazol-2-amine (<i>Pesta</i>) and its heterometallic π,σ-complex [Cu<sub>2</sub>FeCl<sub>2</sub>(<i>Pesta</i>)<sub>4</sub>][FeCl<sub>4</sub>]