Unprecedented Trinuclear Ag<sup>I</sup> Complex with 2,4,6‐Tris(2‐pyrimidyl)‐1,3,5‐triazine as an Efficient Catalyst for the Aziridination of Olefins
Damir A. SafinDepartment of Chemistry, University of Ottawa, 10 Marie Curie Private, K1N 6N5 Ottawa, ON (Canada)Amélie PialatDepartment of Chemistry, University of Ottawa, 10 Marie Curie Private, K1N 6N5 Ottawa, ON (Canada)Ilia KorobkovDepartment of Chemistry, University of Ottawa, 10 Marie Curie Private, K1N 6N5 Ottawa, ON (Canada)Muralee MurugesuDepartment of Chemistry, University of Ottawa, 10 Marie Curie Private, K1N 6N5 Ottawa, ON (Canada)
2015en
ABI
Abstract
An unprecedented trinuclear heteroleptic Ag(I) complex was isolated using a stable multidentate 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine (TPymT) ligand. The obtained compound is an efficient catalyst for the direct aziridination of terminal olefins.
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