A Novel Approach for Synthesis of Carbyne by Electroreductive Polymerization of Diiodoacetylene Catalyzed by Ni Complex
Masashi KijimaInstitute of Materials Science, University of TsukubaYuji SakaiInstitute of Materials Science, University of TsukubaHideki ShirakawaInstitute of Materials Science, University of Tsukuba
1994en
ABI
Abstract
Abstract Diiodoacetylene was electropolymerized with Pt cathode at −2.0 V (vs. SCE) in the presence of Ni complex in dimethylformamide (DMF) under anaerobic conditions, giving an insoluble black powder which had a strong infrared absorption at 2050 cm−1 and a broad Raman peak around 2150 cm−1 due to conjugated polyyne structure. A compressed pellet of the as-prepared sample had an electrical conductivity of 3 × 10−5 S cm−1.
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