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Generating Transferable Tight-Binding Parameters: Application to Silicon

L. GoodwinDepartment of Mathematics, Imperial College - Queen's Gate, London SW7 2BZA SkinnerDepartment of Mathematics, Imperial College - Queen's Gate, London SW7 2BZD. G. PettiforDepartment of Mathematics, Imperial College - Queen's Gate, London SW7 2BZ
1989en
ABI

Abstract

We present a novel method of obtaining transferable tight-binding parameters. The method is applied to Si and new parameters extracted by rescaling the energy functional in a physically transparent manner. Self-consistency is approximated within the tight-binding model by enforcing atomic charge neutrality using a simple algorithm. Results for bulk Si and Si clusters are presented and are seen to agree well with results from accurate ab initio calculations.

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Cited by 40 references