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X-Ray and Magnetization Studies of Cr-Modified<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">Mn</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>Sb

F. J. DarnellCentral Research Department, E. I. du Pont de Nemours and Company, Wilmington, DelawareW. H. CloudCentral Research Department, E. I. du Pont de Nemours and Company, Wilmington, DelawareH. S. JarrettCentral Research Department, E. I. du Pont de Nemours and Company, Wilmington, Delaware
1963lv
ABI

Abstract

The three magnetic states which occur in the Cr-modified ${\mathrm{Mn}}_{2}$Sb system have been studied by measurements of magnetization, torque, and x-ray lattice cell dimension on single crystals. The exchange inversion transitions between magnetic states for a given composition are shown by x ray to be first order. The field dependence of magnetization allows differentiation of the three magnetic states which exhibit ferrimagnetic, intermediate, and antiferromagnetic spin configurations. Torque and magnetization measurements show that for both the ferrimagnetic and antiferromagnetic states there is a change from positive to negative uniaxial anisotropy with decreasing temperature.

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