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Sound Measurements in Liquid and Solid<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msup><mml:mrow><mml:mi mathvariant="normal">He</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math>,<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msup><mml:mrow><mml:mi mathvariant="normal">He</mml:mi></mml:mrow><mml:mrow><mml:mn>4</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math>, and<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msup><mml:mrow><mml:mi mathvariant="normal">He</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math>-<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msup><mml:mrow><mml:mi mathvariant="normal">He</mml:mi></mml:mrow><mml:mrow><mml:mn>4</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math>Mixtures

James H. VignosJosiah Willard Gibbs Laboratory, Yale University, New Haven, ConnecticutH. A. T. FairbankJosiah Willard Gibbs Laboratory, Yale University, New Haven, Connecticut
1966lv
ABI

Abstract

Using the ultrasonic pulse technique at a carrier frequency of 10 Mc/sec, we have measured the longitudinal velocity of sound in liquid and solid ${\mathrm{He}}^{3}$, ${\mathrm{He}}^{4}$, and ${\mathrm{He}}^{3}$-${\mathrm{He}}^{4}$ mixtures (0.0, 5.03, 25.0, 74.9, 98.00, 99.84% ${\mathrm{He}}^{3}$) in the temperature range from 1 to 4.2\ifmmode^\circ\else\textdegree\fi{}K and the pressure range from 1 to 150 atm. An upper limit to the attenuation of sound in the region of the solid investigated is on the order of 0.3 to 0.7 ${\mathrm{cm}}^{\ensuremath{-}1}$. Values of the adiabatic compressibility of the liquid along the melting curve of ${\mathrm{He}}^{4}$ are given. The discontinuity in the propagation velocity at a first-order phase boundary was utilized to locate the solidification curves of these samples and also to investigate the bcc-hcp crystallographic transition in solid samples, including pure ${\mathrm{He}}^{4}$, similar to that observed in pure ${\mathrm{He}}^{3}$ by Grilly and Mills. The triple points for this transition in ${\mathrm{He}}^{4}$ are given by ${T}_{l}=1.449\ifmmode\pm\else\textpm\fi{}0.003$\ifmmode^\circ\else\textdegree\fi{}K, ${P}_{l}=26.18\ifmmode\pm\else\textpm\fi{}0.05$ atm; ${T}_{u}=1.778\ifmmode\pm\else\textpm\fi{}0.003$\ifmmode^\circ\else\textdegree\fi{}K, ${P}_{u}=30.28\ifmmode\pm\else\textpm\fi{}0.05$ atm. The upper triple points for the mixtures lie on a straight line connecting ${\mathrm{He}}^{3}$ and ${\mathrm{He}}^{4}$ in temperature-pressure space. In addition, by observing the peak in the attenuation of sound, it was possible to measure the $\ensuremath{\lambda}$ line in ${\mathrm{He}}^{4}$ and in the 5.0% and 25.0% ${\mathrm{He}}^{3}$ liquid mixtures. The upper $\ensuremath{\lambda}$ point for pure ${\mathrm{He}}^{4}$ is given by ${T}_{s}=1.765\ifmmode\pm\else\textpm\fi{}0.003$\ifmmode^\circ\else\textdegree\fi{}K and ${P}_{s}=29.90\ifmmode\pm\else\textpm\fi{}0.05$ atm. Comparison is made with existing data wherever possible.

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