Cycloartane Glycosides from Cimicifuga dahurica.
Qingwen ZhangDepartment of Phytochemistry, China Pharmaceutical UniversityWen‐Cai YeDepartment of Phytochemistry, China Pharmaceutical UniversityW.L. Wendy HsiaoDepartment of Biology, Hong Kong University of Science and TechnologyShou‐Xun ZhaoDepartment of Phytochemistry, China Pharmaceutical UniversityChun‐Tao CheSchool of Chinese Medicine, The Chinese University of Hong Kong
2001en
ABI
Abstract
A new cycloartane bisdesmoside and two new trinorcycloartane glycosides, along with four known cycloartane compounds, were isolated from the rhizomes of Cimicifuga dahurica (Ranunculaceae). The structures of the new compounds were elucidated as 3-O-alpha-L-arabinopyranosyl cimigenol 15-O-beta-D-glucopyranoside, 24-hydroxy-12beta-acetoxy-25,26,27-trinorcycloartan-16,23-dione 3beta-O-alpha-L-arabinopyranoside, and 16alpha,24alpha-dihydroxy-12beta acetoxy-25,26,27-trinor-16,24-cyclocycloartan-23-one 3beta-O-alpha-L-arabinopyranoside by extensive NMR methods, FAB-MS, and hydrolysis.
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