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Evidence for the dependence of the magnetic ordering on the oxygen occupancy in the high-<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi>T</mml:mi></mml:mrow><mml:mrow><mml:mi>c</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math>superconductor<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mi mathvariant="normal">Gd</mml:mi><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">Ba</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">Cu</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">O</mml:mi></mml:mrow><mml:mrow><mml:mn>7</mml:mn><mml:mo>−</mml:mo><mml:mi>δ</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math>

T. ChattopadhyayInstitut für Festkörperforschung, Kernforschungsanlage Jülich, Postfach 1913, D-5170 Jülich, Federal Republic of GermanyH. MalettaInstitut für Festkörperforschung, Kernforschungsanlage Jülich, Postfach 1913, D-5170 Jülich, Federal Republic of GermanyW. WirgesInstitut für Festkörperforschung, Kernforschungsanlage Jülich, Postfach 1913, D-5170 Jülich, Federal Republic of GermanyK. FischerInstitut für Festkörperforschung, Kernforschungsanlage Jülich, Postfach 1913, D-5170 Jülich, Federal Republic of GermanyP. BrownInstitut für Festkörperforschung, Kernforschungsanlage Jülich, Postfach 1913, D-5170 Jülich, Federal Republic of Germany
1988lv
ABI

Abstract

Neutron-diffraction investigations have been carried out on a single crystal of $\mathrm{Gd}{\mathrm{Ba}}_{2}{\mathrm{Cu}}_{3}{\mathrm{O}}_{7\ensuremath{-}\ensuremath{\delta}}$ ($\ensuremath{\delta}\ensuremath{\simeq}0.5$) to investigate the magnetic ordering of the Gd and Cu moments at low temperatures. Gd${\mathrm{Ba}}_{2}$${\mathrm{Cu}}_{3}$${\mathrm{O}}_{6.5}$ orders at ${T}_{N}=2.2$ K with a wave vector (\textonehalf{}, \textonehalf{}, 0). The Gd moments are antiferromagnetically coupled to their nearest neighbors in the $a\ensuremath{-}b$ plane but are ferromagnetically coupled along the crystallographic $c$ axis in contrast to the case of Gd${\mathrm{Ba}}_{2}$${\mathrm{Cu}}_{3}$${\mathrm{O}}_{7}$ where the coupling along this direction is antiferromagnetic. This result clearly establishes the importance of the oxygen occupancy on the magnetic ordering in $\mathrm{Gd}{\mathrm{Ba}}_{2}{\mathrm{Cu}}_{3}{\mathrm{O}}_{7\ensuremath{-}\ensuremath{\delta}}$ ($0&lt;\ensuremath{\delta}&lt;1$). No evidence for ordering of copper moments was obtained from our present results.

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