Article

Highly Thermally Conductive and Structurally Ultra-Stable Graphitic Films with Seamless Heterointerfaces for Extreme Thermal Management

Peijuan ZhangMOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Key Laboratory of Adsorption and Separation Materials and Technologies of Zhejiang Province, Zhejiang University, 38 Zheda Road, Hangzhou, 310027, People's Republic of ChinaYuanyuan HaoMOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Key Laboratory of Adsorption and Separation Materials and Technologies of Zhejiang Province, Zhejiang University, 38 Zheda Road, Hangzhou, 310027, People's Republic of ChinaHang ShiMOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Key Laboratory of Adsorption and Separation Materials and Technologies of Zhejiang Province, Zhejiang University, 38 Zheda Road, Hangzhou, 310027, People's Republic of ChinaJiahao LuMOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Key Laboratory of Adsorption and Separation Materials and Technologies of Zhejiang Province, Zhejiang University, 38 Zheda Road, Hangzhou, 310027, People's Republic of ChinaYingjun LiuMOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Key Laboratory of Adsorption and Separation Materials and Technologies of Zhejiang Province, Zhejiang University, 38 Zheda Road, Hangzhou, 310027, People's Republic of China. [email protected]Xin MingMOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Key Laboratory of Adsorption and Separation Materials and Technologies of Zhejiang Province, Zhejiang University, 38 Zheda Road, Hangzhou, 310027, People's Republic of China. [email protected]Ya WangInternational Research Center for X Polymers, International Campus, Zhejiang University, Haining, 314400, People's Republic of ChinaWenzhang FangMOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Key Laboratory of Adsorption and Separation Materials and Technologies of Zhejiang Province, Zhejiang University, 38 Zheda Road, Hangzhou, 310027, People's Republic of ChinaYuxing XiaMOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Key Laboratory of Adsorption and Separation Materials and Technologies of Zhejiang Province, Zhejiang University, 38 Zheda Road, Hangzhou, 310027, People's Republic of ChinaYance ChenMOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Key Laboratory of Adsorption and Separation Materials and Technologies of Zhejiang Province, Zhejiang University, 38 Zheda Road, Hangzhou, 310027, People's Republic of ChinaPeng LiMOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Key Laboratory of Adsorption and Separation Materials and Technologies of Zhejiang Province, Zhejiang University, 38 Zheda Road, Hangzhou, 310027, People's Republic of ChinaZiqiu WangMOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Key Laboratory of Adsorption and Separation Materials and Technologies of Zhejiang Province, Zhejiang University, 38 Zheda Road, Hangzhou, 310027, People's Republic of ChinaQingyun SuBeijing Spacecrafts Manufacturing Co., Ltd, Beijing Friendship Road 104, Haidian District, Beijing, 100094, People's Republic of ChinaWeidong LvJi ZhouYing ZhangChina Academy of Aerospace Aerodynamics, Beijing, 100074, People's Republic of ChinaHaiwen LaiWeiwei GaoMOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Key Laboratory of Adsorption and Separation Materials and Technologies of Zhejiang Province, Zhejiang University, 38 Zheda Road, Hangzhou, 310027, People's Republic of ChinaZhen XuMOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Key Laboratory of Adsorption and Separation Materials and Technologies of Zhejiang Province, Zhejiang University, 38 Zheda Road, Hangzhou, 310027, People's Republic of China. [email protected]Chao GaoMOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Key Laboratory of Adsorption and Separation Materials and Technologies of Zhejiang Province, Zhejiang University, 38 Zheda Road, Hangzhou, 310027, People's Republic of China. [email protected]

2023en

ABI

Abstract

Abstract Highly thermally conductive graphitic film (GF) materials have become a competitive solution for the thermal management of high-power electronic devices. However, their catastrophic structural failure under extreme alternating thermal/cold shock poses a significant challenge to reliability and safety. Here, we present the first investigation into the structural failure mechanism of GF during cyclic liquid nitrogen shocks (LNS), which reveals a bubbling process characterized by “permeation-diffusion-deformation” phenomenon. To overcome this long-standing structural weakness, a novel metal-nanoarmor strategy is proposed to construct a Cu-modified graphitic film (GF@Cu) with seamless heterointerface. This well-designed interface ensures superior structural stability for GF@Cu after hundreds of LNS cycles from 77 to 300 K. Moreover, GF@Cu maintains high thermal conductivity up to 1088 W m −1 K −1 with degradation of less than 5% even after 150 LNS cycles, superior to that of pure GF (50% degradation). Our work not only offers an opportunity to improve the robustness of graphitic films by the rational structural design but also facilitates the applications of thermally conductive carbon-based materials for future extreme thermal management in complex aerospace electronics.

Identifiers

DOI: 10.1007/s40820-023-01277-1

Citations and references

Cited by 20 references

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