Статья

Effect of argon impurity on the molar volume of solid CO2

M. A. Strzhemechnyı̆B. I. Verkin Physicotechnical Institute of Low Temperatures, Ukrainian Academy of Sciences, KharkovS. I. KovalenkoB. I. Verkin Physicotechnical Institute of Low Temperatures, Ukrainian Academy of Sciences, KharkovA. A. SolodovnikB. I. Verkin Physicotechnical Institute of Low Temperatures, Ukrainian Academy of Sciences, Kharkov

Soviet Journal of Low Temperature Physicsjournal1992en

ABI

Аннотация

The molar volumes Vm of CO2–Ar solid solutions with an argon concentration c varying between 0 and 100% are measured by using the transmission electron diffraction technique. On the CO2 side, the Vm vs c dependence has a peculiar form of a curve with a peak. A semiquantitative theory proposed for explaining this which takes into account not only the spherical component of interaction between particles in the solution, but also the presence of anisotropic forces in solutions rich in the molecular component.

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Темы

Phase Equilibria and Thermodynamics Chemical Thermodynamics and Molecular Structure Thermodynamic properties of mixtures

Идентификаторы

DOI: 10.1063/10.0033338

Цитирования и источники

Цитирований: 0Использованных источников: 1

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