Synthesis and structure of complexes of Co(II) acetate and Zn(II) chloride with 2-aminobenzothiazole
Shakhnoza KadirovaUlugbek National University of Uzbekistan, Vuzgorodok, Tashkent, 700174, UzbekistanM. R. TursunovaUlugbek National University of Uzbekistan, Vuzgorodok, Tashkent, 700174, UzbekistanM. M. IshankhodzhaevaSt. Petersburg State Technological University of Plant Polymers, St. Petersburg, RussiaN.A. ParpievUlugbek National University of Uzbekistan, Vuzgorodok, Tashkent, 700174, UzbekistanЗ. КаримовTashkent Institute of Irrigation and Melioration, Tashkent, UzbekistanA.G. TozhiboevYunusov Institute of Chemistry of Plant Substances, Academy of Sciences of Uzbekistan Republic, Tashkent, UzbekistanБ. ТашходжаевYunusov Institute of Chemistry of Plant Substances, Academy of Sciences of Uzbekistan Republic, Tashkent, Uzbekistan
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Аннотация
Complexes of Co(II) acetate and Zn(II) chloride with 2-aminobenzothiazole were prepared, and their structures were studied by IR spectroscopy and single crystal X-ray diffraction. The complexes have the composition [Co(CH3COO)2(2-aminobenzothiazole)2] and [Zncl2(2-aminobenzothiazole)2]. The coordination core has a distorted tetrahedral configuration. The metal ion coordinates two nitrogen atoms of the thiazole rings and two oxygen atoms of acetate ligands or two chloride ions.
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