Статья

2,2′-Dihydroxybiphenyl-3,3′-dicarbaldehyde dioxime

Ekaterina GolovniaKiev National Taras Shevchenko University, Department of Chemistry, Volodymyrska str. 64, 01601 Kiev, UkraineElena V. PrisyazhnayaKyiv National University of Construction and Architecture, Department of Chemistry, Povitroflotsky Ave., 31, 03680 Kiev, UkraineTurganbay S. IskenderovKarakalpakian University, Department of Chemistry, Universitet Keshesi 1, 742012 Nukus, UzbekistanMatti HaukkaIgor O. FritskyKiev National Taras Shevchenko University, Department of Chemistry, Volodymyrska str. 64, 01601 Kiev, Ukraine

Acta Crystallographica Section E Structure Reports Onlinejournal2009en

ABI

Аннотация

The mol-ecule of the title compound, C(14)H(12)N(2)O(4), lies across a crystallographic inversion centre situated at the mid-point of the C-C intra-annular bond. The mol-ecule is not planar, the dihedral angle between the aromatic rings being 50.1 (1)°. The oxime group is in an E position with respect to the -OH group and forms an intra-molecular O-H⋯N hydrogen bond. In the crystal structure, inter-molecular O-H⋯O hydrogen bonds link mol-ecules into chains propagating along [001]. The crystal structure is further stabilized by inter-molecular stacking inter-actions between the rings [centroid-to-centroid distance = 3.93 (1) Å], resulting in layers parallel to the bc plane.

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Темы

Crystal structures of chemical compounds Synthesis and biological activity Crystallography and molecular interactions

Идентификаторы

DOI: 10.1107/s1600536809029298

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