Hydrothermal synthesis of two supramolecular inorganic–organic hybrid phosphomolybdates based on Ni(<scp>ii</scp>) and Co(<scp>ii</scp>) ions: structural diversity and heterogeneous catalytic activities
Luna PaulDepartment of Chemistry Jadavpur UniversityMalay DolaiDepartment of Chemistry Jadavpur UniversityAnangamohan PanjaIndiaMahammad AliDepartment of Chemistry Jadavpur University
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Two new compounds (NHEPH<sub>2</sub>)<sub>5</sub>[Ni<sup>II</sup>(P<sub>4</sub>Mo<sub>6</sub>O<sub>31</sub>)<sub>2</sub>]·6H<sub>2</sub>O (<bold>1</bold>) and {(NHEPH<sub>2</sub>)<sub>2</sub>[Co<sup>II</sup>(H<sub>2</sub>O)<sub>6</sub>]}[P<sub>2</sub>Mo<sub>5</sub>O<sub>23</sub>]·2H<sub>2</sub>O (<bold>2</bold>) exhibited heterogeneous styrene oxidation by H<sub>2</sub>O<sub>2</sub> under mild conditions.
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