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Current state and perspectives for organo-halide perovskite solar cells. Part 1. Crystal structures and thin film formation, morphology, processing, degradation, stability improvement by carbon nanotubes. A review

N. R. AshurovScience Centre of Chemistry and Physics of Polymers, National University of Uzbekistan named after Mirzo Ulugbek, 7b A. Kadyri Str., Tashkent 100128, UzbekistanБ. Л. ОксенгендлерScience Centre of Chemistry and Physics of Polymers, National University of Uzbekistan named after Mirzo Ulugbek, 7b A. Kadyri Str., Tashkent 100128, UzbekistanС. Е. МаксимовScience Centre of Chemistry and Physics of Polymers, National University of Uzbekistan named after Mirzo Ulugbek, 7b A. Kadyri Str., Tashkent 100128, UzbekistanSayyora RashiodvaScience Centre of Chemistry and Physics of Polymers, National University of Uzbekistan named after Mirzo Ulugbek, 7b A. Kadyri Str., Tashkent 100128, UzbekistanA. R. IshteevEnergy Efficiency Center, National University of Science and Technology MISiS, 4 Leninskiy Prospekt, Moscow 119049, RussiaD. SaraninEnergy Efficiency Center, National University of Science and Technology MISiS, 4 Leninskiy Prospekt, Moscow 119049, RussiaIgor BurmistrovEnergy Efficiency Center, National University of Science and Technology MISiS, 4 Leninskiy Prospekt, Moscow 119049, RussiaДенис КузнецовEnergy Efficiency Center, National University of Science and Technology MISiS, 4 Leninskiy Prospekt, Moscow 119049, RussiaAnvar A. ZakhisovDepartment of Physics, University of Texas at Dallas, 800 West Campbell Road, Richardson, TX 75080-3021, USA
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Аннотация

The fundamental problems of the modern state of the studies of organic–inorganic organo-halide perovskites (OHP) as basis for high efficiency thin film solar cells are discussed. Perovskite varieties and background properties are introduced. The chronology of development of the studies in this direction has been presented – structural aspects of these OHP perovskites, from early 2D to recent 3D MAPbI3 perovskites and important technological aspects of smooth thin film structure creation by various techniques, such as solvent engineering, spin- and dip - coating, vacuum deposition, cation exchange approach, nanoimprinting (particularly, a many-sided role of polymers). The most important theoretical problems such as electronic structure of lattice, impurity and defect states in pure and mixed perovskites, suppressed electron-hole recombination, extra-long lifetimes, and diffusion lengths are analyzed. Degradation effects associated with moisture and photo irradiation, as well as degradation of metallic electrodes to OHP solar cells have been considered. The application of carbon nanostructures: carbon nanotubes (CNT) and graphene as stable semitransparent charge collectors to OHP perovskites is demonstrated on the example of original results of authors.

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